Bouling Group Co., Ltd

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Diethylenetriamine (DETA): An Insider’s Take

Historical Development

In the chemical world, few stories travel as far back as the journey of amines. Diethylenetriamine, often found shortened as DETA, stands out as a staple among polyamines with a legacy colored by innovation and necessity. Chemists in the early 20th century took notice of DETA for its unique structure and reactive character. Early industrial players saw its promise in polymer production and surfactant applications, planting it firmly into the roots of modern manufacturing. Over years and generations, DETA moved out from chemistry textbooks and into the backbone of countless processes, from corrosion inhibitors to adhesives and textile finishing. Its development closely tracks the rapid growth of synthetic fibers and resins in the post-war period, shedding light on how closely society’s progress and chemistry’s advances intertwine.

Product Overview

Anyone who has come across a drum of DETA recognizes its utility stretches beyond a niche product. You’ll find it in pure, technical, and formulated grades, often tailored for precise demands in manufacturing or research labs. DETA’s molecular structure teases out versatility—three nitrogen atoms spaced across a five-carbon chain, creating a backbone fit for endless chemical tailoring. Product forms range from clear, colorless to pale yellow liquids, their character shaped by the level of purity, stabilization needs, and packaging choices. In industrial supply, DETA often ships in large bulk containers, but also shows up in lab bottles for fine-tuned synthesis work.

Physical & Chemical Properties

Folks handling DETA quickly learn its physical quirks matter in daily operations. It shows up as a slightly viscous, hygroscopic liquid with a faint ammoniacal odor that hits hard in a closed space. At room temperature, DETA’s boiling point clocks in above water at 207°C, which impacts both safety protocols and processing equipment. Water solubility sits high, giving it an open door for blending and reaction in aqueous systems. Its basicity and nucleophilicity set it apart; DETA’s three amine groups crave reactions with acids, epoxides, and a range of organic molecules, making it a strong candidate for forming salts, curing agents, and complexes with metals.

Technical Specifications & Labeling

Specification sheets for DETA make clear calls on purity, moisture, color, and secondary component levels. Most industrial batches hit over 98% purity, pulling moisture content down to sub-percent levels to avoid unwanted side reactions. On containers, labels provide the familiar hazard warnings—corrosive, harmful on skin contact, toxic if ingested. Any worker worth their training checks for clear UN and CAS numbers, GHS symbols, and storage advice before moving a barrel. Transport requires adherence to international protocols; you won’t see responsible firms risking leakage or contamination with slipshod handling.

Preparation Method

Preparation of DETA traditionally flows from the reaction of ethylene dichloride with ammonia in the presence of catalysts. Down the line, you see hydrochloride salt intermediates converted to free amine using caustic. Some plants run continuous reactors where temperature and pressure dial in the yield, while outdated approaches used more batchwise addition. Byproduct separation plays a big role, as reactions typically yield a mixture of ethylenediamine, triethylenetetramine, and higher homologues, meaning distillation and purification become critical steps. Process chemists keep a close eye on energy use, waste treatment, and raw material sourcing, all of which bear on the bottom line and environmental footprint.

Chemical Reactions & Modifications

DETA’s real charm comes through in its chemistry toolbox. Its primary and secondary amines lay out multiple reactive sites, opening the door for alkylation, acylation, and crosslinking. Epoxy curing is a heavy draw—here, DETA reacts with epoxide groups, lending resilience and adhesion to floor coatings, wind turbine blades, and composite structures. In the oil field, DETA fans out into corrosion inhibitors, complexing agents, and scouring compounds due to its ability to pair with metals or basic anionic groups. Chemists often functionalize DETA by grafting longer alkyl chains or by building dendritic structures, feeding into textile treatment, water purification, or specialty surfactants. Going down this route, the opportunities for custom modification seem just about endless.

Synonyms & Product Names

In catalogs and supplier listings, DETA appears under many aliases. Common synonyms include 2,2'-Iminodi(ethylamine), N-(2-Aminoethyl)ethane-1,2-diamine, and Pentamethylenediamine. Some specialty chemical vendors give their own brand twist, naming it under house codes or blends. Industrial users just call it DETA to keep things short, knowing any seasoned buyer can track it by CAS 111-40-0.

Safety & Operational Standards

Anyone who spends time near DETA learns respect for its hazards. Contact with skin can burn, and inhaling vapors risks throat and lung irritation; eye exposure brings painful consequences. Industry best practice means gloves, goggles, face shields, and efficient ventilation—you don’t skimp on respiratory protection around large volumes. Every storage area places DETA in tightly sealed drums or tanks, set away from oxidizers and acids that could set off heat, pressure, and destructive reactions. Emergency preparedness drills matter; staff need muscle memory on spill handling, first aid, and quick access to eyewash stations. OSHA, REACH, and local agencies set legal standards on permissible exposure and waste management, pushing for regular training and monitoring.

Application Area

Look across industries—DETA leaves fingerprints everywhere. Epoxy resin curing soaks up big tonnage, especially where strength and chemical resistance make or break a product. Textile manufacturers leverage DETA for softeners and anti-static finishes, modernizing everything from carpets to athletic wear. Water treatment outfits count on polyamine-based flocculants and chelating agents to pull out heavy metals and scale from municipal and industrial streams. In the oil patch, DETA-based additives keep pipelines clear and engines clean. And, for folks working in personal care or home cleaning, DETA acts as an intermediate, building blocks for surfactants and specialty amines that keep products safe and stable on the shelf.

Research & Development

Laboratories and research groups keep searching for the next leap with DETA. Polymeric networks built from DETA-derived branches show promise in drug delivery and biomedical scaffolds, potentially changing how we think about tissue repair or targeted therapy. Chemically modified versions already attract attention for use in next-generation water splitting, battery electrolytes, or as building blocks for greener surfactants. Academics and corporate labs dive deep into how structural tinkering tunes reactivity, stability, or environmental persistence, keeping the spirit of innovation alive. And the patent streams keep coming—complexes for rare earth recovery, catalysts for carbon capture, functional coatings, and reactive dyes all tap into DETA’s adaptability.

Toxicity Research

DETA’s safety record shows its double edge. Acute exposures risk skin and respiratory damage, while repeated contact can sensitize and trigger allergic responses. Animal studies point to moderate toxicity, with particular risk to eyes, mucous membranes, and lungs. Chronic exposure links to liver and kidney effects in some test systems. Environmentally, DETA breaks down in soil and water yet shows some toxicity to aquatic life before dilution or treatment. Regulators in North America, Europe, and Asia track its use and emissions, signaling the need for engineered controls—not shortcuts—to keep workers, communities, and ecosystems safe.

Future Prospects

DETA faces new horizons as regulatory and market pressure asks for safer, more sustainable chemistry. Demand for more efficient resins and stronger, cleaner water purification keeps research growing. Bio-based routes, recycling methods, and greener formulations draw interest from both startups and industry giants. Health and environmental studies will likely keep shaping how DETA finds use—some applications may drop by the wayside, while new, low-impact uses could dominate future supply. As needs shift, smart players watch the science, stay nimble on regulations, and keep investing in product stewardship and application know-how. That’s the way this story keeps on unfolding—product evolution joined to real-world need.



What are the main industrial applications of Diethylenetriamine (DETA)?

Practical Uses of DETA on the Factory Floor

Factories don’t run on big names and cutting-edge slogans—they rely on chemicals like Diethylenetriamine, or DETA for short. Out on the shop floor, few people think about how a pale-yellow liquid can keep systems moving, but look closely, and DETA turns up just about everywhere. DETA starts with the basics: it’s a simple, three-nitrogen amine. That modest structure sets it up as a multitasker across chemical plants and workshops.

Epoxy Curing Agents

Anyone working with epoxy-based products finds DETA hard to ignore. Its presence matters most in curing agents. Epoxy resins stay sticky and unusable without the right amine to crosslink their molecules. DETA offers short cure times and yields tough, heat-resistant bonds. I’ve seen this quality in the adhesives holding wind turbine blades together and in strong coatings laid on factory floors. Resins that rely on DETA can take a beating: chemical spills, temperature swings, tire tracks—none of these faze them much.

Corrosion Inhibitors and Oil Refineries

Talk to maintenance workers in pipelines and oil refineries, and the conversation will shift to rust. Rust stoppage isn’t glamorous, but DETA-based inhibitors earn their keep here. By forming a protective layer on steel, DETA reduces the time and money spent on emergency repairs. Refineries dealing with sour gas or water know this first-hand. In oilfield recovery, DETA-based products extend the life span of assets under attack from brine or carbon dioxide.

Water Treatment and Chelation

Municipal water treatment doesn't make headlines, yet it’s here that DETA steps up again. Water supplies packed with heavy metals and hardness ions clog pipes and mess up processes downstream. Companies use DETA to grab those troublesome ions before they enter the municipal system or end up in finished products. This work matters most for food processors, power stations, and dye houses—places where clean water matters every day. In household laundry detergents and soaps, DETA-derivatives help soften water, improving cleaning results and preventing mineral scale.

Making Resins and Polymers

Anyone who’s mixed up two-part adhesives or resins for boat building has met DETA’s influence. Resin makers use DETA to produce polyamides and polyurethanes, giving parts flexibility and chemical resistance. DETA-based polymers wind up in everything from automotive hoses to medical tubing. In the paper and textile industries, DETA acts as a building block in fixing agents that keep dyes from leaching and paper fibers stuck together, giving a lasting finish without frequent touch-ups.

Looking to the Future

Switching to greener production won’t happen overnight, but DETA continues to earn its place by offering reliable performance in recycling and sustainable chemistry projects. For instance, some companies are now pushing for DETA in biodegradable surfactant production. The science on these applications holds promise, but it rests on practical experience—from operators mixing reaction batches to engineers keeping streams in spec.

DETA doesn’t grab newspaper headlines, but its fingerprints stretch across multiple industries. Whether keeping welded joints strong, pipelines clear of rust, or water safe to drink, this chemical keeps things running behind the scenes. In a world where industries strive to cut costs and downtime, DETA’s value remains clear. Experience and trust come from results seen on the ground, and so DETA keeps showing up where real work gets done.

What is the chemical formula and structure of DETA?

The Formula Behind DETA

DETA stands for diethylenetriamine. The chemical formula reads as C4H13N3. You get this by combining four carbon atoms, thirteen hydrogen atoms, and three nitrogen atoms. In practice, that means three nitrogen atoms strung together with two ethylene (–CH2CH2–) groups between them, each nitrogen finding its place in the chain. If you’ve ever seen a simple stick-and-ball drawing, it looks like a zigzag with three points for the nitrogens.

Molecular Structure You Can Recognize

The backbone of DETA’s structure starts with one amine group at each end and a secondary amine in the middle. Written out, it’s H2N–CH2CH2–NH–CH2CH2–NH2. This simple setup gives DETA flexibility as well as reactivity. Each nitrogen atom can participate in chemical bonding, letting the molecule link with a lot of chemical partners. That’s one main reason folks see it all over the place in industry and laboratories.

DETA’s Importance in Industry

My time working alongside folks in water treatment, coatings, and chemical processing taught me that DETA acts as something of a workhorse. The multiple amino groups make it a good chelating agent. It can grab hold of metal ions—something that helps keep water systems running cleanly. In epoxy resins, DETA helps control the hardening process, influencing the final strength and durability of materials. Chemists use it as a building block to build up even more complex ingredients for pharmaceuticals or surfactants. It doesn’t just sit on a shelf; it shows up wherever flexibility and strong chemical bonding matter.

Why Safety and Handling Matter

The story isn’t always about what a molecule can do, though. DETA brings with it some concerns for health and environment. Exposure, especially to skin and eyes, quickly produces irritation. I learned early on not to open a bottle of DETA carelessly, even for a quick demonstration. Its vapors have a sharp ammonia-like smell, serving as a warning to stay cautious. OSHA sets workplace limits for amine compounds like DETA, so gloves, goggles, and good ventilation are the standard. Cleaning up spills with care keeps people and property safe.

DETA and Sustainability

Many companies today talk more about the impact of chemicals once they leave the plant. DETA does not hang around in the environment the way heavier, halogenated chemicals do. Microorganisms can break it down, and that biodegradability counts for something when evaluating long-term effects. No use pretending it’s risk-free, but compared to some of its alternatives, DETA offers a less persistent environmental footprint. That said, responsible handling and disposal need attention from start to finish.

Paths Forward

Innovation comes from understanding the whole picture. For DETA, this means recognizing where it’s already “pulling its weight”—like in wastewater treatment or polymer chemistry—and looking for ways to minimize any downsides. Some folks are already tweaking production processes to curb emissions and improve worker safety. In labs and factories, the push is on to recycle amine-based compounds or switch to greener solvents where possible. The lessons learned from DETA ripple out to the way we handle all chemical building blocks: Respect their strengths, handle with care, search for improvements.

What are the safety precautions and handling guidelines for DETA?

What You Need to Know Before Handling DETA

Diethylenetriamine, or DETA, comes up in all kinds of manufacturing—from resins to lubricants, adhesives, and even water treatment chemicals. Across workshops, folks who handle it daily understand how important safety really is. DETA can cause burns, breathing issues, and might irritate skin or eyes on contact. Without careful steps, accidents happen quickly, and their effects can linger.

Why Personal Protective Equipment Isn't Just Extra Gear

Too many people think safety goggles or gloves are optional. I’ve seen burns and serious eye injuries from just a few splashes. DETA needs a full set: chemical-resistant gloves, goggles or a shield, and a lab coat or apron that covers skin. Thick nitrile or neoprene gloves block the kind of exposure regular latex won’t. Goggles can mean the difference between a scare and a hospital visit. Respiratory gear—often overlooked—matters most when you handle DETA in places without good airflow. A cartridge respirator designed for organic chemicals helps avoid lung irritation.

Keep the Air Moving—Ventilation Really Matters

A lot of small shops skip on ventilation, especially when budgets get tight. Fume hoods and exhaust systems take the most harmful vapors outside, instead of letting them hang around where folks breathe. If you can smell anything sharp, odds are the air isn’t moving enough. I always recommend testing hoods and fans with something simple—like a smoke stick or incense—just to see which way the air carries it.

Handling and Storage: Don't Let Lids or Labels Slip

Too often, rushed workers leave containers open, or relabel them with a marker that can wear off. That kind of carelessness multiplies risk, especially after shift changes and in shared spaces. DETA should live in tightly sealed drums or bottles, marked with chemical names everyone on the shop floor recognizes. No storing near acids or oxidizers—DTETA reacts strongly and causes dangerous fumes or fires if mixed. A cool, dry storage spot out of direct sun stops containers from degrading or bursting.

Spill Response: Keep It Simple and Swift

A small spill handled quickly with absorbent pads, baking soda, and plenty of water keeps minor messes from turning into long shutdowns. Where I used to work, every station kept a bin with absorbent powder, gloves, and a face shield—used often enough to prove its worth. If someone gets DETA on their skin, rinsing with water for at least 15 minutes often prevented scars or lasting pain. Eye-wash stations and safety showers should always be within a short walk—no worker should scramble looking for them in an emergency.

Training: Experience Becomes the Best Prevention

Mistakes drop off fast when everyone knows what to look for and how to fix problems before they spread. Training sessions with real scenarios, not just printed manuals, stick with teams longer. People need to practice using spill kits, fitting respirators, and working with fume hoods so instinct takes over during a hectic moment.

Improving Safer Workplaces, One Detail at a Time

Safer workplaces start with keeping protective gear ready, checking storage and ventilation, and always labeling chemicals clearly. Leading by example encourages everyone in a shop to pay attention. Good habits, like fixing labels or swapping out worn gloves, save money, protect workers, and build a culture where accident-free days become the rule. That’s real peace of mind for anyone who works with DETA or chemicals like it.

How should DETA be stored and transported?

Why Proper Handling Matters

Storage and transport seem simple right up until something goes sideways. DETA—diethylenetriamine for those new to the term—offers plenty of benefits in manufacturing, but a spill or a leak can shut down a plant and spark real health risks fast. Coming from a background where chemical safety briefings were as regular as morning coffee, mishandled drums have left stains both on loading docks and, more seriously, on people’s health records.

Understanding the Real Hazards

If DETA leaks or evaporates in an uncontrolled space, it can irritate eyes, skin, and lungs. Some workers have developed long-term sensitivities. Not every shop has a top-notch ventilation system, and in the heat of peak summer, vapors build up quickly. DETA will react with copper and its alloys, so pipes or containers that work for other chemicals can fail here. You can’t simply grab whatever tank is handy and call it a day.

The flash point for DETA sits at around 108°C, which sounds like plenty of buffer, but I’ve watched careless storage in direct sunlight push drum temperatures dangerously close. Once one vent is triggered, the whole warehouse can follow suit.

Safe Storage: Proven Practices

A well-ventilated, cool, and dry area works best for storing DETA. No cardboard boxes, no shared space with acids or oxidizers—just dedicated facilities with floors that keep chemical leaks from heading directly into groundwater. Steel containers with strong seals make a difference.

In my experience, taking shortcuts breeds headaches. One client stacked barrels too high, hoping to save floor space, and wound up with dented drums and a minor but expensive leak. Stacking should stay under the manufacturer’s recommended height—about two high for safety. Signage should be bold, clear, and posted at all entrances, so nobody stumbles into an accident out of ignorance. Personal protective equipment doesn’t sit in a dusty corner; gloves, goggles, and chemical-resistant aprons go on every time.

Transport: Don’t Leave Safety at the Dock

The Department of Transportation in the US treats DETA as hazardous material. Using UN-certified drums and properly labeled containers keeps the shipment legal—and much safer for everyone else on the road. Flatbeds need proper securing gear, and drivers should check seals before departure. In the chaos of busy shipping operations, supervision and checklists force a second look and can prevent accidents before they roll out the gate.

I’ve talked to truckers who learned the value of spill kits the hard way. A well-stocked kit isn’t a finicky extra; it offers a lifeline if a drum tips in traffic or a valve gives out during offloading. Routes should avoid tunnels and densely populated city centers where possible—collateral damage from a minor spill can compound fast in tight quarters.

Training and Communication: Small Investments, Big Impact

No equipment fixes reckless habits. I’ve seen turnover in loading docks leave new hires without any meaningful orientation. Running even a quick hands-on demo of how to spot damaged containers or handle minor leaks builds better habits and trust. Regular safety meetings aren’t just corporate box-checking, they anchor safety culture. Nearly every incident I’ve investigated came from missed communication or skipped steps during handoffs.

Better Systems Start With Accountability

All those rules and checklists exist for a reason. Everyone, from warehouse staff to truck drivers, benefits from clear expectations and steady oversight. Digital logs now help track chemical batches and drum conditions much better than the old clipboard approach, flagging aging containers before anyone gets exposed. If a facility’s leadership looks the other way, corners will get cut—even seasoned workers follow a leader’s real priorities.

In the end, storing and transporting DETA safely rarely costs much extra. The real risk comes from rushing the simple steps or assuming someone else will catch a problem in time.

What are the typical packaging sizes and purity grades available for DETA?

Why DETA Packaging Matters

DETA, or Diethylenetriamine, finds its way into a toolbox of industries. Anybody who’s worked in water treatment, epoxy hardening, or chemical processing can quickly tell the difference between a productive work site and a headache: it's the packaging and the purity. Whether you're running a lab or managing a warehouse, the ultra-specific demands of different processes make it important to know exactly what you’re buying and how it’s delivered.

Common Packaging Sizes

Bulk buyers often lean toward steel drums—usually 200-liter or 55-gallon sizes—since those big blue barrels hold up well through rough handling and shipping. That means less worry about punctures or leaks before the product hits the shop floor. For smaller outfits, or for those needing precision batches, you’re looking at 25-liter or even 10-liter HDPE containers. While these sizes move easier and store better for smaller operations, transport costs per liter can creep up.

In industrial zones, I’ve watched how moving a drum with a forklift instead of wrestling with multiple jugs smooths the job. Still, not every application uses that much DETA at once. Some research labs or specialty manufacturers use 1-liter or 2.5-liter bottles sealed against air and moisture. This smaller packaging tries to answer the call for convenience and avoids wastage. Across every size, strict labelling spells out lot numbers and handling warnings—government and internal audits drill this point home.

Purity Grades: What They Mean in Practice

Not all DETA is created equal. The bulk grade, typically advertised at 98%, usually solves problems in large-scale manufacturing—think oilfield chemicals or resin curing. Most engineers don’t want to pay extra for lab-grade purity in these settings.

Laboratories and the pharmaceutical sector have different needs. High-purity grades can reach 99% or more, cut for scenarios where each contaminant might ruin an experiment or damage equipment. Instruments performing analysis require this kind of reliable quality. There’s a premium for high purity, and smaller packaging follows suit. These products come with robust data sheets detailing analysis results, so buyers see exactly what levels of water content, color, and trace amines sit inside each bottle.

The Connection to Safety and Quality

Safety gets extra attention with DETA. Low impurity levels help protect workers and improve results in finished goods. In my own experience in the chemical supply trade, end users check every incoming drum with a quick titration or even a sniff test—for DETA, “fishy” odors point to amine content, signaling it hasn’t absorbed a bunch of water or degraded on the shelf. Manufacturing managers set procedures for rotating stock, and keep records that can be checked if results in production change suddenly.

What Leads the Choices

Economics and end use drive most packaging and grade decisions. Smaller firms might start with intermediate containers and ramp up size as they scale orders. Tight budgets can push users to select lower-purity grades, then discover through trial that higher grades reduce re-work and product defects, saving money long term. For some formulations, it’s not just about pure DETA, but also about controlling things like water content, which affects how it reacts downstream.

Open communication with suppliers and staying current on industry standards — these habits help buyers avoid delivery delays, poor-fit packaging, or unexpected impurities. Reading up before ordering has prevented costly mistakes more than once in my own work with specialty chemical buyers.

Diethylenetriamine(DETA)
Names
Preferred IUPAC name 2,2'-Iminodi(ethylamine)
Other names 2,2′-Iminodi(ethylamine)
N-(2-Aminoethyl)ethane-1,2-diamine
Bis(2-aminoethyl)amine
Pronunciation /daɪˌɛθ.aɪliːnˈtraɪ.ə.miːn/
Identifiers
CAS Number 111-40-0
Beilstein Reference 1710809
ChEBI CHEBI:16199
ChEMBL CHEMBL142986
ChemSpider 7271
DrugBank DB01987
ECHA InfoCard ECHA InfoCard: 03-2119471486-30-0000
EC Number 203-865-4
Gmelin Reference 65823
KEGG C02327
MeSH Diethylenetriamine
PubChem CID 8030
RTECS number KU9100000
UNII GAK48F80A2
UN number UN2071
Properties
Chemical formula C4H13N3
Molar mass 103.17 g/mol
Appearance Clear, colorless to pale yellow liquid
Odor Ammonia-like
Density 0.955 g/cm³
Solubility in water miscible
log P -2.04
Vapor pressure 0.4 mmHg (20°C)
Acidity (pKa) 10.9
Basicity (pKb) pKb = 3.04
Magnetic susceptibility (χ) -62.7×10⁻⁶ cm³/mol
Refractive index (nD) 1.471
Viscosity 1.7 mPa·s (at 20°C)
Dipole moment 2.38 D
Thermochemistry
Std molar entropy (S⦵298) 205.7 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -113.2 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -3746.7 kJ/mol
Pharmacology
ATC code V03AB04
Hazards
GHS labelling GHS05, GHS07, GHS08
Pictograms GHS05, GHS06, GHS07, GHS08
Signal word Warning
Hazard statements H302, H314, H317, H319, H412
Precautionary statements P261, P264, P272, P273, P280, P302+P352, P305+P351+P338, P310, P321, P333+P313, P362+P364, P391, P501
NFPA 704 (fire diamond) 3-1-0
Flash point > 93 °C
Autoignition temperature 930 °F (499 °C)
Explosive limits 2.3% - 10.4%
Lethal dose or concentration LD50 (oral, rat): 1080 mg/kg
LD50 (median dose) 1080 mg/kg (Rat, oral)
NIOSH WAJ36750
PEL (Permissible) PEL: 1 ppm (parts per million)
REL (Recommended) 10 ppm
IDLH (Immediate danger) 50 ppm
Related compounds
Related compounds Triethylenetetramine
Ethylenediamine
Tetraethylenepentamine