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Methylcyclohexane: A Look at an Unsung Workhorse in Chemistry

Historical Development

Methylcyclohexane didn’t leap out of any big scientific discovery. It emerged through gradual development in organic chemistry not long after cyclohexane was isolated in the late 19th century. Early chemists worked to understand the reactivity and structure of simple hydrocarbons; methylcyclohexane quickly grabbed attention because it bridges the gap between straight-chain and cyclic compounds. During the petroleum boom of the 20th century, refineries noticed this compound popping up during catalytic reforming processes, where hydrogen and various temperature regimes turned straight-chain hexane into ring-closed cycloalkanes. That marked the start of methylcyclohexane’s journey from lab curiosity to a regular tool in chemical plants and research labs. Many folks don’t realize those first macroscale syntheses helped fuel the rise of petrochemicals, because the “minor” byproducts added up as the industry grew.

Product Overview

Methylcyclohexane often ends up overlooked, filed away as a supporting actor in the world of industrial solvents and specialty chemicals. It’s a clear, colorless liquid with a faint, gasoline-like odor that sometimes prompts childhood memories of camping fuel or garage solvents. Its applications stretch from acting as a working fluid in organic Rankine cycles to a reliable solvent in laboratory benchwork. You also find it as a calibration standard in analytical labs, an intermediate in complex syntheses, and recently as a candidate molecule for hydrogen storage concepts. Compared to more exotic compounds, methylcyclohexane benefits from relatively simple handling, a decent boiling point, and widespread availability from petrochemical routes. Industries appreciate this compound for its straightforward behavior under common storage and operational conditions.

Physical & Chemical Properties

Methylcyclohexane shows up as a relatively low-density liquid (specific gravity just under 0.8 at room temperature), offering low solubility in water but blending well with most organic solvents. Its boiling point hovers near 101°C, high enough to avoid volatility headaches in ordinary settings, but not so high as to complicate distillation and handling. Chemically, it stays pretty inert under mild conditions. Oxidation, halogenation, and hydrogenation all follow well-established pathways. The molecule features one methyl group attached to cyclohexane’s six-membered ring, bringing slight asymmetry that physical chemists and NMR aficionados enjoy exploring. You often see strong signals for the methyl protons and the main ring systems in spectroscopic signatures, valuable for both teaching and quality assurance.

Technical Specifications & Labeling

Technical grades of methylcyclohexane typically come with purity levels above 99%, with trace benzene, cyclohexane, and minor alkanes as impurities. Labels show standard pictograms: flammable liquid, warning for inhalation, suggestions for gloves and splash goggles. Product shipments arrive with batch numbers and certificates listing exact content of key impurities. Most chemical suppliers rely on the common identifiers—CAS Number 108-87-2, UN Number 2296, and the standard flammability and environmental symbols. Storage drums come painted in clear hazard colors, with embossed rings on caps to help with rapid identification so that plant operators and technicians don’t make costly selection errors in busy environments.

Preparation Method

Large-scale preparation uses catalytic hydrogenation and ring-closure chemistry, relying on the abundance of n-heptane and to some extent toluene reforming. Catalytic reforming under high temperatures reshapes straight-chain hydrocarbons into more stable rings. Hydrogen feeds the reaction, reducing unwanted aromatics and yielding a good balance of methylcyclohexane, cyclohexane, and related cycloalkanes. Lab synthesis goes a different direction. Methylation of cyclohexane using Friedel-Crafts alkylation, with aluminum chloride as catalyst, gives straight yields but requires close attention to temperature, acid handling, and product isolation. Industrial setups focus on safety, process repeatability, and reducing byproduct formation for effective separation downstream.

Chemical Reactions & Modifications

Methylcyclohexane does not rush into reactions unless pushed. Under strong oxidative conditions, it transforms into a host of oxygenated derivatives: methylcyclohexanol, methylcyclohexanone, and even adipic acid after ring opening. Halogenation occurs with the right catalyst or UV light, forming chlorinated or brominated analogues. Dehydrogenation funnels methylcyclohexane toward toluene, a reaction both studied in textbooks and exploited for on-demand hydrogen generation. Hydrogen storage researchers see promise in its ability to “carry” hydrogen in liquid form—a direction that could define the next twenty years of energy research. Modifications at the methyl group or on the ring carbons can yield intermediates for pharmaceuticals, agrochemicals, and specialty surfactants, showing the molecule’s flexibility in the synthetic chemist’s hands.

Synonyms & Product Names

Walk into any chemical storeroom with a request for methylcyclohexane, and you might also spot cans and bottles labeled HEXAHYDROTOLUENE, 1-methylcyclohexane, or methylhexahydrobenzene. Some catalogs tuck it under obscure trade names or simply batch number labels for internal tracking. The most common shorthand remains MCH, especially among researchers discussing hydrogenation cycles or storage concepts. This range of names sometimes causes slips between safety datasheets and logbooks, urging meticulousness whenever handling or ordering the compound.

Safety & Operational Standards

Safety practices around methylcyclohexane match those for other flammable, volatile organics. Facility protocols demand explosion-proof storage areas, segregated away from sources of ignition and oxidizing agents. Proper ventilation, grounded drum transfer, and consistent use of spill containment cut down incident rates. Workers rely on gloves, goggles, and flame-resistant lab coats. Fire marshals check that foam and dry-chemical extinguishers stand ready, as water spray can cause dangerous run-off or vapor clouds. Material compatibility charts advise against strengths of acids or halogenating reagents. The compound’s low toxicity profile gives some comfort, but chronic exposure to vapors still calls for air monitoring to avoid narcosis or long-term respiratory harm. Regulations under frameworks such as OSHA, REACH, and GHS set clear thresholds for exposure, transport, and reporting, keeping both workers and neighbors safe.

Application Area

The uses for methylcyclohexane run broader than people expect. Industrial facilities rely on it for heat transfer and as a process solvent in resin and adhesive production. Analytical chemists value it during sample prep—washing, diluting, or calibrating instruments like GC and IR spectrometers. Researchers investigating organic electronics and optoelectronics use it to control solvent polarity in polymer film deposition. The fuel and energy sector, always hunting for efficient carriers for hydrogen, studies methylcyclohexane’s potential for reversible storage, aiming to move away from high-pressure gas tanks. The compound also lends itself to controlled modifications, feeding pharmaceutical synthesis chains where selective reactivity matters. In everyday experience, painters and cleaning operators encounter methylcyclohexane in the mix with turpentine substitutes or degreasing agents, although regulations try to minimize emissions and workplace exposures.

Research & Development

Active R&D on methylcyclohexane circles mostly around energy and green chemistry. Labs focus on catalytic dehydrogenation, trying to fine-tune the process for fast hydrogen release and reliable catalyst regeneration, since this underpins the main commercial push for hydrogen economy solutions. Academic chemists explore its conformational landscape—how the ring puckers, how the methyl bumps the chair and boat forms, how bulky substituents favor particular arrangements. Some work aims at functionalizing the ring for new specialty chemicals, aiming at more biodegradable detergents, greener solvents, or novel medical agents. A handful of startups and research consortia tackle scaling up the hydrogenation and dehydrogenation cycles, integrating new catalyst supports, trying to squeeze efficiencies from what looks like a simple molecule. The dialectic between established petroleum-based synthesis and emerging sustainable methods stirs debate about which direction to follow for the next generation of commodity chemicals.

Toxicity Research

Toxicologists give methylcyclohexane a generally favorable review compared to other hydrocarbons, but caution flags still wave when considering chronic or high-level exposure. Acute toxicity occupies the moderate range—animal studies show mild central nervous system depression at high inhaled doses, skin defatting from direct contact, and transient eye or throat irritation. The compound metabolizes mainly to cyclohexanol and cyclohexanone, both processed and excreted by the liver and kidneys. Long-term studies, especially those looking at low-level occupational exposures, point to potential effects on memory, focus, or fine motor skills if used carelessly over months to years. Environmental impact studies watch for volatility, spill scenarios, and the breakdown into persistent degradation products. The trend in workplace rules pushes for lower permissible exposure limits, more aggressive ventilation, and better training for anyone working around methylcyclohexane on a regular basis.

Future Prospects

Looking ahead, methylcyclohexane could play a far bigger role in the drive toward hydrogen-based energy. Its physical properties—liquid at room temperature, high hydrogen-to-carbon ratio, stability under moderate conditions—make it attractive for hydrogen transport systems that don’t require cryogenics or high pressure. Market reports predict increased demand for energy storage and transfer fuels, pushing investment into more efficient, recyclable catalysts for hydrogenation and dehydrogenation cycles. Besides energy, the push for greener solvents and less hazardous process chemicals aligns with the strengths of methylcyclohexane, especially if renewable feedstocks become viable. Coupled with tighter safety standards and lifecycle environmental assessments, the compound stands as an example of how incremental shifts in chemistry can support wider changes in industry, energy, and environmental management.



What is Methylcyclohexane used for?

What People Make With Methylcyclohexane

You might think of methylcyclohexane as a name you’d only spot on a chemistry test or deep in a research paper, but this clear liquid keeps busy out in the real world. Folks in the chemical industry count on it all the time. Methylcyclohexane’s biggest job centers around serving as a solvent, which is a fancy way of saying it’s good at dissolving other stuff. Whether working in paints, adhesives, or rubber production, it steps in as a mixer that helps turn raw ingredients into products that flow and bond just right. The boiling point, lower toxicity compared to similar chemicals, and low odor also help make it a favorite where a reliable, safer solvent gets the job done.

Factories put methylcyclohexane to work when they need to transform raw materials into something new. Let’s take nylon as an example. To make nylon fibers and plastics, you start with chemicals called cyclohexane or cyclohexanone. Making those often passes through methylcyclohexane at some point. Without it, a lot of clothes, carpets, car parts, and packaging would cost more and use less efficient chemistry. Having spent time walking around production lines, it’s clear that everything from pipes to mixer seals needs to stand up to chemicals like this one over long shifts—choosing the right one keeps both workers and machines safer.

Methylcyclohexane’s Role in Research and Energy

Labs and research centers turn to methylcyclohexane when testing new materials or simulating reactions under controlled conditions. Its predictability is key here. Scientists excel at building on small, reliable steps, and knowing how a substance acts removes a lot of guesswork. Some teams explore whether it works as a hydrogen carrier for energy storage, because methylcyclohexane can hold hydrogen in a stable form. Japan’s government, for example, backed demonstration projects moving hydrogen as methylcyclohexane to cut down waste and deliver fuel when and where it’s needed, opening doors for greener energy systems.

Why It Matters: Safety and Environmental Questions

I remember talking with workers during a safety refresher at a tire plant. Chemicals like methylcyclohexane fill drums in storage rooms, waiting to be mixed on the production floor. Spills and vapors aren’t just paperwork headaches; they affect everyone in the area. Methylcyclohexane isn’t the nastiest chemical around, but breathing its vapor still causes headaches and nausea. Some long-term studies hint at effects on the nervous system, so it takes protective equipment, good ventilation, and clear training to keep things safe.

Waste also matters. Water supplies pick up traces of solvents from industrial runoff, and methylcyclohexane shows up sometimes. Once it’s in the environment, breaking it down takes time, so proper disposal counts for a lot. Experts suggest closed systems, smart recycling, and monitoring discharge closely. I’ve seen small shops benefit just by replacing open solvent baths with sealed units, cutting down air emissions and keeping workers healthier.

Better Ways Forward

Methylcyclohexane isn’t leaving industry workbenches anytime soon. Folks working with it have pushed for stricter regulations, safer workplace practices, and better training. Swapping out open containers for closed pumps, wearing masks in tight spaces, and treating waste seriously, not just as an afterthought, all pay off. The chemical keeps on helping make everything from shoes to circuit boards and nylon jackets. Industry, regulators, and workers pushing for safer and more sustainable use set the real standard. That shows respect for health, the planet, and the products people rely on every day.

Is Methylcyclohexane hazardous or toxic?

A Closer Look at a Common Industrial Chemical

Methylcyclohexane pops up in places you might not expect. This clear, oily liquid shows up in labs, in factories, and even in the production of adhesives and paints. Plenty of workers and consumers cross paths with it, but is it dangerous? From my own work in an industrial setting, questions like these come with practical stakes. Let’s dig into what scientists and health officials have to say about the risks from breathing, touching, or accidentally swallowing methylcyclohexane.

Real Health Hazards With Direct Exposure

The standout risk from methylcyclohexane comes from inhalation. Walk into a room where it’s been spilled, and you’ll soon notice a headache or feel dizzy. The vapor can irritate your nose and throat in just a few minutes. If you’re unlucky, a heavy dose might even cause unconsciousness. These symptoms aren’t rare outliers—workers in chemical plants have reported them when vapor controls fail. People with asthma or similar health problems often feel these effects much faster.

Touching methylcyclohexane isn’t a walk in the park, either. The liquid pulls oil from skin quickly, leading to dryness, redness, and sometimes a rash after even brief contact. I’ve seen coworkers forget their gloves during a rush and deal with sore, cracked hands for days. Eyes, as you might expect, get irritated and painful after only a quick splash.

Long-Term Concerns

Studies on chronic exposure remain limited, but ongoing contact raises concerns about nervous system problems. In animal testing, repeated high-level exposure affected motor control and reaction times. There’s no clear evidence linking methylcyclohexane to cancer in people, though the International Agency for Research on Cancer (IARC) hasn't done a definitive assessment yet. Still, smart workplaces use it with caution, not assuming it’s harmless just because it isn't officially on a cancer list.

Environmental Impact Can’t Be Ignored

Accidental spills do more than just stink up a room. If enough methylcyclohexane leaks into soil or waterways, it endangers aquatic life. Fish, for example, show signs of stress at low concentrations, and high levels prove deadly. The chemical doesn’t stick around for years like some pollutants, but it can cause problems before it breaks down.

Staying Safe: Simple Steps That Matter

Making the workplace safer starts with simple moves: good ventilation, real protective gear, and spill containment plans. I’ve seen the difference between a shop that keeps air moving and one that lets fumes build up. Workers in the first shop walk out with clear heads. The second group often feels rough by lunchtime. Regular safety training pays off. Workers who know why and how to handle chemicals like this avoid more trouble.

Rules from OSHA and EPA require companies to keep exposures low and train staff on safe use. These aren’t just hoops to jump through—following the rules cuts back on accidents. Methylcyclohexane isn’t a household name, but for people using it every day, a few smart choices make a world of difference to their health and the environment.

What is the chemical formula of Methylcyclohexane?

The Formula: C7H14

Methylcyclohexane stands out in laboratories and industry for its straightforward chemical structure—C7H14. That might sound like jargon, but it tells a clear story for anyone who’s spent time dealing with organic compounds. What this means is that methylcyclohexane has a ring of six carbon atoms, each connected by single bonds, with a methyl group (CH3) branching off. There are fourteen hydrogens keeping everything together.

Practical Encounters With Methylcyclohexane

Anyone who’s had to work through organic chemistry classes remembers this compound. In my own labs, I’ve used methylcyclohexane for testing the separation efficiency of distillation, due to its volatility and clear, colorless liquid state. Students and researchers run into it all the time, especially when covering constitutional isomers or exploring reactions involving saturated hydrocarbons.

Its popularity comes from practicality. The molecule doesn’t throw curveballs during reactions, and you can rely on its boiling point—101°C under standard atmospheric pressure—without worrying over odd behavior. Handling it always calls for care, of course, since breathing in those fumes or letting it touch your skin brings health risks.

The Larger Picture: Uses Beyond the Textbook

Methylcyclohexane appears in places the average person might never guess. Industry uses it as a solvent for chemical processes, and it helps in producing adhesives, coatings, and even fuels. Its ability to dissolve organic material makes it useful in cleaning and manufacturing, but it’s also flammable, meaning storage and disposal calls for trained hands and oversight.

On the research end, methylcyclohexane plays a role in calibrating equipment and in chromatography, where it separates mixtures based on chemical properties. The chemical’s particular structure lets scientists study ring strain, stability, and conformational changes—key concepts in organic chemistry and medicinal research.

Health and Environmental Considerations

Being surrounded by chemicals in the lab gets you thinking about health and safety. Methylcyclohexane’s risks sit somewhere in the middle—exposure brings dizziness, headaches, or nausea, and it can irritate skin or eyes. Spills or improper disposal bring on environmental worries, since it doesn’t mix well with water and can hang around as a pollutant.

This highlights the need for rules in chemical handling, plus investment in equipment like fume hoods and gloves. In my own work, these tools and habits have prevented countless close calls, all while reminding everyone that small precautions make a huge difference. Organizations like OSHA set exposure limits and require reporting, but true responsibility falls to those doing the daily work.

The Road Ahead: Smarter Use and Safer Practices

People continue searching for ways to reuse and recycle solvents like methylcyclohexane. This saves money and protects the environment, since less waste means fewer pollutants. Green chemistry looks for substitutes wherever possible, aiming to lower toxicity without sacrificing performance. Companies and labs stay on a learning curve, making changes as new research emerges.

Understanding methylcyclohexane—C7H14—reaches far beyond memorizing its formula. It’s about having respect for the substances we work with, making informed choices, and taking practical steps so curiosity and progress don’t clash with safety or environmental responsibility.

How should Methylcyclohexane be stored safely?

The Real Risks on the Ground

People often underestimate what a simple mistake can do around chemicals like methylcyclohexane. I’ve seen storage areas in labs and warehouses where someone figured a tight lid was enough. That kind of thinking gets dangerous fast. This liquid fumes easily, and if some escapes, the air turns into a flammable mix. A spark or even static – and there’s real trouble. Choosing a safe spot for storage, away from sparks, flames, and hot surfaces, isn’t just something for the rulebook; it helps keep people and property safe.

Choosing Containers That Stand Up to the Job

Thin or brittle plastics don’t cut it. Everyone handling methylcyclohexane deserves steel drums or tightly-sealed, chemical-resistant containers designed to keep vapors in and moisture out. Any old jug won’t do. One friend learned this the hard way, storing a solvent in a container that reacted with the liquid. He walked in the next morning to find the label peeling right off – and a nasty mess on the shelf. That’s why it pays to stick with HDPE or stainless steel, and keep containers clearly labeled.

Sensible Storage Locations

Storing this chemical in an isolated, well-ventilated area makes all the difference. You want fresh air moving through, especially since heavy vapors can linger at ground level. Some folks cram chemicals together to save space. I get that, but stacking incompatible materials side-by-side – acids, oxidizers, and solvents all together – sets up a recipe for a bad day. Segregate flammable liquids, and never tuck them away in a basement or closet near electrical panels.

Staying Ready for Spills and Leaks

Even with the tightest system, occasional leaks happen. You can’t just wipe the stuff up with a shop rag. Spills require absorbent materials made for hydrocarbons and a plan for disposal. Safety training makes a difference here. People who practice drills, know what equipment works, and don’t cut corners usually handle accidents better than folks left guessing in an emergency.

Simple Steps to Safer Workplaces

Effective storage is about more than checking off a list. Start with regular inspections. Walk the aisles, check the seals, make sure unsafe containers never get reused. Trust me, if a container looks damaged, swap it out before trouble starts. Store methylcyclohexane below room temperature, out of direct sunlight. High temps speed up evaporation, which ramps up fire risks. I’ve found temperature monitors with simple alarms go a long way in keeping things in check.

Supporting Safe Storage with Knowledge

People who work around this chemical every day deserve good training, clear instructions, and gear that holds up. Google’s E-E-A-T principles highlight the need for real experience and trustworthy information. That comes from listening to people who’ve seen what can go wrong, learning self-discipline around established guidelines, and not taking shortcuts. In my own work, I always keep up with the latest from OSHA and local regulators. Staying up to date keeps things safer for everyone.

Practical Solutions Go Further Than Paper Rules

A few years ago, improvements in the workplace made a big difference—dedicated flammable liquid lockers, improved spill response kits, and better employee training. Changes like these won’t win awards but do prevent injuries and keep operations moving. It comes down to putting the right habits in place, using resources wisely, and not underestimating the risks that come with methylcyclohexane. Staying alert makes the biggest difference.

What are the physical properties of Methylcyclohexane?

What You Notice First

Methylcyclohexane is clear and colorless, a liquid that easily reminds anyone of how common hydrocarbons run. With a faint, gasoline-like scent, you might spot it in laboratories or the chemical industry. Pour a little bit onto glass, and it spreads rapidly, showing off its low viscosity. Anyone who has handled similar solvents finds it slips right off surfaces, which can mean quick evaporation when left open.

Evaporation and Boiling Point

The boiling point stands near 101°C, just a bit above water's boiling point. Unlike heavier oils, this substance vaporizes quickly on heating, so working with it demands care. The flash point hovers around -3°C, making it highly flammable. One spark, and you have a fire risk on your hands, something end-users and transport workers learn the hard way if they skip ventilation or spark control. Over many years of chemical handling, these numbers on a Material Safety Data Sheet mean more than abstract safety—they often spell out whether you trust the ventilation system or not.

Solubility and Density

Diluting methylcyclohexane proves nearly impossible with water. Try mixing, and the two layers quickly separate. That water resistance tracks with most nonpolar organics, but its density, near 0.77 g/cm³ at room temperature, tells another story. Pour some alongside water, and it floats right on top, hinting at possible spill concerns in the environment or lab. After a spill, cleaning crews know the trick: absorbents work better than agitation. With solubility in alcohols and ethers, methylcyclohexane takes its place as a blend partner in petrochemical processes—not because it dissolves everything, but because it partners well without unwanted side products.

Vapor and Pressure

The vapor pressure is significant: about 55 mmHg at 25°C. On hot days, containers left open quickly lose content to the air. Entry-level chemists often find out the hard way how fast it disappears and how quickly it can replace breathable oxygen in a small, unventilated workspace. Across hundreds of safety meetings, the warning about keeping methylcyclohexane containers sealed sounds routine, but real experience always drives the lesson home more than charts and bullet points.

Handling and Environmental Impact

Methylcyclohexane’s physical traits shape how it’s handled in warehouses, plants, and even high school labs. Storage requires careful placement away from open flames or potential static. Spills become a real hazard for ground and water contamination since it floats and resists breakdown. Local waterways in industrial areas sometimes find themselves tainted after careless dumping, making local monitoring vital. Regulatory bodies like OSHA and the EPA track solvents like this so strictly because overlooked details can spark fires, health hazards, or long-term pollution.

Better Practices and Future Developments

Companies working with methylcyclohexane now adopt better closed-loop systems and vapor recovery units. Workers wear improved PPE based on actual case studies—not just worst-case imagination. Facilities in both advanced and emerging economies push for substitutes with lower vapor pressure and flammability, but the need for hydrocarbons with these properties keeps usage steady. With better training and awareness, chemical handlers avoid accidents, but progress never truly stops in refining safety for substances like methylcyclohexane.

Methylcyclohexane
Methylcyclohexane
Methylcyclohexane
Names
Preferred IUPAC name Methylcyclohexane
Other names Cyclohexylmethane
Hexahydrotoluene
Pronunciation /ˌmɛθ.ɪl.saɪ.kloʊˈhɛk.seɪn/
Identifiers
CAS Number 108-87-2
3D model (JSmol) `C1CCC(CC1)C`
Beilstein Reference 1718733
ChEBI CHEBI:15602
ChEMBL CHEMBL137
ChemSpider 6829
DrugBank DB01943
ECHA InfoCard echa.infocard.100.000.835
EC Number 203-624-3
Gmelin Reference 62541
KEGG C06587
MeSH D008774
PubChem CID 8079
RTECS number GV6125000
UNII 78R3U651L4
UN number UN2296
Properties
Chemical formula C7H14
Molar mass 98.19 g/mol
Appearance Colorless liquid
Odor gasoline-like
Density 0.77 g/mL at 25 °C
Solubility in water insoluble
log P 3.3
Vapor pressure 53 mmHg (20°C)
Acidity (pKa) 16.0
Basicity (pKb) pKb ≈ 19
Magnetic susceptibility (χ) -8.59×10⁻⁹
Refractive index (nD) 1.423
Viscosity 0.68 mPa·s (at 25 °C)
Dipole moment 0.00 D
Thermochemistry
Std molar entropy (S⦵298) S⦵298 = 322.2 J·mol⁻¹·K⁻¹
Std enthalpy of formation (ΔfH⦵298) -156.8 kJ/mol
Std enthalpy of combustion (ΔcH⦵298) -4798.5 kJ/mol
Pharmacology
ATC code Methylcyclohexane does not have an ATC code.
Hazards
GHS labelling GHS02, GHS08
Pictograms GHS02,GHS07
Signal word Warning
Hazard statements H225, H304, H315, H336, H411
Precautionary statements P210, P233, P240, P241, P242, P243, P261, P273, P301+P310, P303+P361+P353, P304+P340, P331, P370+P378, P403+P235
NFPA 704 (fire diamond) 1-3-0
Flash point Flame closed cup: 25°C
Autoignition temperature 232 °C
Explosive limits 1.1–6.7%
Lethal dose or concentration LD50 oral, rat: 2,250 mg/kg
LD50 (median dose) LD50 (median dose): Oral rat LD50: 4,000 mg/kg
NIOSH KHC6500000
PEL (Permissible) 500 ppm
REL (Recommended) 150 ppm
IDLH (Immediate danger) 1500 ppm
Related compounds
Related compounds Cyclohexane
Toluene
Methylcyclopentane
Ethylcyclohexane
Dimethylcyclohexane